Thursday, July 28, 2011

Wall thickness

 Just as metals have normal working thickness ranges based upon their processing method, so do plastics. Typically, for injection molded parts, the wall thickness will be in the range 0.5 mm to 4 mm (0.02 - 0.16 in). Dependent on the part design and size, parts with either thinner or thicker sections can be molded.
While observing functional requirements, keep wall thicknesses as thin and uniform as possible.  In this way even filling of the mold and anticipated shrinkage throughout the molding can be obtained in the best way.  Internal stresses can be reduced.
Wall thickness should be minimized to shorten the molding cycle, obtain low part weight, and optimize material usage.  The minimum wall thickness that can be used in injection molding depends on the structural requirements, the size and geometry of the molding, and the flow behavior of the material.  As a starting point the designer can often refer to spiral flow curves which give a relative measure of the maximum achievable flow length for a given wall thickness and injection pressure. See figure below.

Spiral flow length of Akulon Ultraflow at 260° and 1400 bar.

If parts are subjected to any significant loading the part should be analyzed for stress and deflection. If the calculated stress or deflection value is not acceptable a number of options could be considered including the following:

  • Increase wall (if not already too thick)
  • Use an alternative material with higher strength and/or modulus
  • Incorporate ribs or contours in the design to increase the sectional modulus

Other aspects that may need to be considered include:

Insulation characteristics
Generally speaking insulating ability (whether for electrical or heat energy) is related to the thickness of the polymer.

Impact characteristics
Impact resistance is directly related to the ability of a part to absorb mechanical energy without fracturing. This in turn is related to the part design and polymer properties. Increasing the wall section will generally help with impact resistance but too thick (stiff) a section may make a design unable to deflect and distribute an impact load therefore increasing stresses to an unacceptable level.

Agency approval
When a part design must meet agency requirements for flammability, heat resistance, electrical properties etc, it may be necessary to design with thicker sections than would be required just to meet the mechanical requirements.

Where varying wall thicknesses are unavoidable for reasons of design, there should be a gradual transition (3 to 1) as indicated in the figure below.

Gradual transition of wall thicknesses. 
 
Generally, the maximum wall thickness used should not exceed 4 mm. Thicker walls increase material consumption, lengthen cycle time considerably, and cause high internal stresses, sink marks and voids (see figure below).

Sink marks due to large wall thicknesses.
Voids due to large wall thicknesses.
 
Care should be applied to avoid a "race tracking" effect, which occurs because melt preferentially flows faster along thick sections. This could result in air traps and welds lines, which would appear as surface defects. Modifying or incorporating ribs in the design can often improve thick sections.

Influence of rib design on flow behavior of the melt.
 

Example of design study of multi-connector.
 
 

General Design Guidelines

Although component design is complex, following a few fundamental principles will help minimize problems during injection molding and in part performance. In some instances it may not be possible to incorporate or follow all the suggested advice but the guidelines should increase your understanding of designing with thermoplastics.

Design recommendations
Wall thickness
Ribs and profiled structures
Gussets or support ribs
Bosses
Holes
Radii & Corners
Tolerances
Coring
Undercuts
Draft angle

Overview of design principles

The process of developing thermoplastic parts requires a full understanding of typical material properties under various conditions. Thermoplastics can be categorized by their molecular structure as either amorphous, semi-crystalline plastics, or liquid crystal polymers (LCPs). The microstructures of these plastics and the effects of heating and cooling on the microstructures are shown in the figure below.

Molecular structure of thermoplastics.




Amorphous thermoplastics
Amorphous polymers have a structure that shows no regularity. In an unstressed molten state polymer molecules are randomly oriented and entangled with other molecules. Amorphous materials retain this type of entangled and disordered molecular configuration regardless of their states. Only after heat treatment some small degree of orientation can be observed (physical aging).

When the temperature of the melt decreases, amorphous polymers start becoming rubbery. When the temperature is further reduced to below the glass transition temperature, the amorphous polymers turn into glassy materials. Amorphous polymers possess a wide softening range (with no distinct melting temperature), moderate heat resistance, good impact resistance, and low shrinkage.

Semi-crystalline thermoplastics
Semi-crystalline plastics, in their solid state, show local regular crystalline structures dispersed in an amorphous phase. These crystalline structures are formed when semi-crystalline plastics cool down from melt to solid state. The polymer chains are partly able to create a compacted structure with a relatively high density. The degree of crystallization depends on the length and the mobility of the polymer segments, the use of nucleants, the melt, and the mold temperatures.

Liquid crystal polymers
Liquid crystal polymers (LCPs) exhibit ordered molecular arrangements in both the melt and solid states. Their stiff, rod-like molecules that form the parallel arrays or domains characterize these materials.



The difference in molecular structure may cause remarkable differences in properties. Various properties are time or temperature dependent. The shear modulus, for instance, decreases at elevated temperatures. The shear modulus curve illustrates the temperature limits of a thermoplastic

The shape of the curve is different for amorphous and semi-crystalline thermoplastics. Glass transition temperature (Tg) and melt temperature (Tm) are indicated in figure below.


The following graph demonstrates time dependent creep moduli.  In general semi-crystalline materials have lower creep rates than amorphous materials. Glass reinforcement generally improves the creep resistance of a thermoplastic material.

Rotational Molding



Introduction
Rotational molding (RM), also called rotomolding or rotational casting, is a process for producing bellow, seamless items of all sizes and shapes.  The molded products range from domestic tanks to industrial containers, from small squeeze – bulbs to storage vessels for highly corrosive materials.   Commercial and industrial containers for packaging and materials handling may be covers and housings, water softening tanks and tote boxes; bay cribs, balls, doll parts; display figures; sporting equipment such as golf carts, surfboards, footballs, juggling pins, helmets; playground equipment and games; housings for vacuum cleaners, scrubbers, and lawnmowers; traffic barricades; display cases; boat hulls (Fig. 13.1); and so on.

Rotational moulding can produce quite uniform wall thickness even when the part has a deep draw of the parting line or small radii.  Ti is also useful if other techniques make it impossible to obtain a uniform wall thickness when molding a flat surface, especially if the surface has a large area.  The liquid or powdered  plastic used in this process flows freely into corners or other deep draws upon the mold being rotated and is fused/melted by heat passing through the mold’s wall.

This process is particularly cost-effective for small production runs and large part sizes; the molds are not subjected to pressure during molding, so they can be made relatively inexpensively out of thin sheet metal.  The molds may also be made from lightweight cast aluminum and electroformed nickel, both of them light in weight and low in cost.  Large rotational machines can be built economically because they use inexpensive gas-fired or hot-air ovens with the lightweight mold-rotating equipment.

Large parts range from up to 22000gal (83m³) in size, with a wall thickness of 1.5in. ((38mm). One tank this size used 2.4 tons (5300lb).

Processing
In most operations the mold cavities are filled with a certain amount of liquid or powder (charging the molds); the mold halves are clamped or bolted together; the charged and closed mold is then placed in a heating oven and the equipment biaxially rotates the mold during the heating cycle.  During heating, the plastic material melts, fuses, and densifies into the shapes of the internal cavities by directional centrifugal forces.  After heating is competed, the molds are moved into a cooling chamber where they continue to rotate and are slowly cooled by air from a high-veiocity fan and / or by fine spray of water.  After removal from the cooling chamber, the molds are opened and the solidified products are removed. 

Although RM machines can be built very inexpensively, they are lab-intensive.  Both rotations have to be programmed, either at the same rate or at different rates, depending on the product shape.  The temperature and duration of the heating cycle also need to be dontrolled.  Most machines that are being built have horizontal rotating arms with closed, recirculating, high-velocity, hot air ovens, with total automation of the compete process.  Many of these machines are also computer programmed to obtain consistent product quality.  The most common combine recirculating hot-air, gas-fires ovens with molds made of cast aluminum or fabricated sheet metal.  Fast operation is achieved by having four positions; load, heat, cool, and unload.  They use four arms, each holding a mold; thus, each positon is constantly in use.

More conventional RM uses three-position machines, where one arm is used for unloading and loading, followed by heat and cool (Fig. 13.2).  figure 13.3 shows the feeding inlet to form hollow products inside a closed mold while the mold is heated and rotated about two axes.  This system allows different plastics to be molded in multilayers; it is called corotational molding.

Different designs are used to meet different processing requirements: caroused, shuttle, clamshell, rock-and-roll machines, and so on.  Shuttle machines are principally used for rotational molding of large products such as tanks.  A frame for holding one mold is mounted on a movable table.  The table is on a tract which allows the mold and the table to incve into and out of the oven.  After the heating period is complete, the mold is moved into an open cooling station.  A duplicate table with a mold moves into the heating oven, usually from the opposite side of the oven.

As one mold is being cooled, the other mold is in the heating stage, and so on.

The clamshell machines have only one arm.  The same location provides mold loading, heating, cooling, and unloading.  It uses an enclosed oven that also serves as the cooling station.

The rock-and-roll technique is popular for molding long products such as canoes and kayaks.  It rotates on one axis and tilts to provide action in the other axial direction.  Most of the motion is in the long direction of the product, which relates to the main rotating motion.


Molds
Cost aluminum molds are most frequently used, especially for small to medium-size products.  Cast aluminum has better heat transfer than steel and is very cost-effective when several molds for the same part are required.  Sheet metal molds are normally used for larger parts.  They are easy to produce since sections can be welded together.  Since the molds are not subjected to pressure during molding, they are not built to take the high loads required in molds for injection, compression, and other pressure operating molds (Chapters 2,4,8).

Two –piece molds are usually used but molds in three or more pieces are sometimes required to remove the finished products.  Molds can be as simple as a sphere, and molds can be complex with undercuts, ribs, and /or tapers.  Design considerations include heat transfer, mounting techniques, parting lines, clamping mechanisms, mold releases, venting and material stability in storage and during the RM process.

Mold – release agents are usually required because the plastic melt may adhere to the surface of the mold cavity, particularly if the cavity has a very complex shape with contours, ribs, etc.  many molds must have very little or no draft, so they require a  mold-release agent.  There are mold-release agents that can be baked or applied to the cavity by wiping.  By coating with fluorocarbon, the need for mold release could be eliminated.  With conventional RM, after the initial mold-release agent is applied, several hundred parts can usually be molded before a stripdown of the mold cavity is required and another baked on coating is applied.

Most rotational molds require a venting system to remove the gas that develops during the heat cycle.  Venting of mould is also used to maintain atmospheric pressure inside the closed mold during the entire cycle of heating and cooling.  The vent ill reduce flash and prevent mold distortion as well as lowering the clamping pressure needed to keep the mold closed.  It will prevent blowouts caused by pressure and permit use to thinner molds.  The vent can be a thin-walled tube with an internal liner of PTFE.  The opening where enters the mold is located where it will not harm the performance or appearance of the molded product. 

Materials
Most RM resins are in powder form with a particle size of 35 mech (74-2000µm).  The other form is liquid.  Some high-flow resins, such as nylon, have been used in small pellet form.  About 85 wt% of molding applications use polyethylenes, particularly LDPE, LLDPE, HDPE and cross linked grades of PE (XLPE and other grades).  Ethylene vinyl acetate and adhesive PEs are also used in specialized applications as are PVC, PC, TP polyester, nylon, and PP.

Costing
Advantages exist with rotational molding since costs for molds and equipment are lower than those of most other processing methods.  Channels for cooling water and resistance to clamping force are not needed.  Different products and colors may be molded on the same machine and in the same cycle.  Quick mold changes are possible when several short production runs are required.  Large, hollow parts are conveniently molded.  Trimming can be eliminated because very little flash is produced.  The molded parts are relatively stress-free.  Corner sections are thicker than with other processes, processes, which provides additional strength when required.  Undercuts, molded-in inserts, intricate contours, and double-wall construction are routinely included.

The essential characteristics of thermoplastic sheet material namely that when they are heated to just below molting point they become rubbery or plastic in nature to an extent which enables them to be attachment out rather like a balloon.  They thus display a good hot melt strength and it is this feature which enables various types of sheet materials to be successfully formed.

Plastics sheet is manufactured by the main processes like extrusion, calendaring and casting.  In general, the greatest proportion of sheet is produced by the continuous extrusion or calendaring process with thickness ranging from 0.15mm to 12.5mm.

Thermoforming Materials
The materials most generally used for forming may be listed as follows:
Polystyrene (PS), Acrylo-nitrile-butadiene –styrene (ABS), Polyvinyl Chloride (PVC ), Acrylic (PMMA), Cellulose-acetate-butyrate (CAB) Polycarbonate (PC) and Polypropylene (PP).

Thermoforming molds
Wood, plaster, cement, metal epoxy or polyesters.   For forming prototypes and small batch quantities,  wood or plaster moulds may be used.  Hard wood is frequently employed but for long production runs epoxy resin or polyester resin coated are to be preferred.  For long runs cast and machined aluminium and steel moulds are preferred when durability, rapid cooling is required.  The moulds  must be drilled with a number of small holes for evacuating or supplying air.

Heating arrangements
Electric resistance heaters are used from one or both side of the sheet. 
Process
The mould is places over the air outlet.  The plastics sheet to be formed is placed over the open top of machine (box) and clamped down by the frame, thus sealing –off the box and making it an airtight  compartment.  The heater panel is them placed over the plastics sheet at a distance of 5-6 in .  (127 – 156mm) in order to heat the sheet as uniformly as possible.  When the sheet has been raised to a temperature below its melting point, the heater is withdrawn and air is evacuated by means of the evacuated by means of the vacuum pump.  This causes the plastic sheet to be sucked down into or over the mould and to form an accurate reproduction of the mould contours.  The mould can be either male or female or a combination of both, when the sheet has cooled and hardened the clamping frame is then released, the formed sheet removed from the mould and the surplus material trimmed-off.
The cycles of a vacuum forming sheet is :
-         Clamping of the sheet, heating of the sheet, forming of the sheet, cooling of the sheet, and removal of the sheet.
Thermoforming or vacuum forming machine consists of a vacuum pump, clamping  frame, a heating panel, air compressor and mould.
Different type of thermoforming or vacuum forming methods are :
-         Straight vacuum forming in a female mould
-         Drape forming on a male mould
-         Pre-stretched by the bubble or air assist method
-         Plug assist vacuum forming
-         Matched mould or die forming
Process variables in thermoforming
-         Materials variations :
1.   Sheet thickness :- Thickness variations should not be over 4-8% for high quality production it can be caused dye to
i)             Uneven heating      ii)       Uneven drawing          iii) or both.
2.   Sheet viscosity can melt index variations mainly applicable to olefins
3.   Sheet orientation : - For maximum uniformity, the sheet used must be un oriented.
4.   Sheet density :-  Variations in sheet density  (especially of olefins) can cause variations in tensile strength, shrinkage, hardness, stiffness and softening temperature.
-         Process variables:
1.   Heating temperature and final sheet temperature
2.   Prestreching
3.   Air or plug temperatures :- Air and / or plugs used to prestrech or form the port should be kept at controlled temperature to insure maximum uniformity of the part.
-         Mold variables
1.   Vacuum holes :- These should be as small as possible, so that no marks will be on the final part.  Slots are better than holes, but are more expensive.
2.   Speed of evacuation : In general, the faster the evacuation, the better the part will form.
3.   Mold temperatures : Mold temperature can affect the forming of part and final size by affecting shrinkage.  If size variations cannot be tolerated, optimum temperature has to be maintained.
4.   Mold Surface :- If varies depending on polymer processed.  For PE, a lightly sandblasted surface will suffice.

The Importance of Thermal Insulation Plate


Thermal insulation plates are very important components for stabilizing the temperature of the mold or injection molding and for realizing energy savings for temperature maintenance. These are used as mandatory components in the injection molding of engineering plastics or super engineering plastics.

In general, the methods of using thermal insulation plates are the following two.
1.When using by fixing to the platen of the injection molding machine.
2.When using by fixing at the back of the mold mounting plate
The following items are the criteria for selecting thermal insulation plates.

1. Heat resistance temperatureAs a guideline, the following recommended usage temperatures can be used.
-Recommended usage temperature of 100°C or less
-Recommended usage temperature of 180°C or less
-Recommended usage temperature of 220°C or less
-Recommended usage temperature of 400°C or less
-Recommended usage temperature of 500°C or less

2. Material
The material is related to the recommended usage temperature and the strength of compression.
The following are the types of materials used.
-Cotton cloth + phenol plastic (Bakelite)
-Craft paper + phenol plastic (Bakelite)
-Glass fiber + silicate powder
-Glass fiber + ultra heat resistant epoxy resin
-Glass fiber + phosphate powder
-Glass fiber + borate powder

Texture and Steel Materials


Texture is used for providing artificial undulation patterns or texturing on the surface of molded products.
"Texture" engraves undulations on the surface of the cavity similar to "etching", or "sandblasting".
In texture, etching, an acidic corrosive liquid is made to come into contact with and erodes the surface of the steel material under managed conditions.
When carrying out texturing, the technique is to pay attention to the following points.
(1) The surface roughness of the cavity surface should be polished as finely as possible.
Further, even the extent of polishing should be as uniform as possible.
When this is done, even the state of erosion of the undulations easily becomes uniform. If there are variations in the undulation pattern, the visual beauty perceived by the human eye may appear to be of a different nature. For example, the appearance of beauty seen under sunlight may be different from the appearance of beauty seen under the light of a white fluorescent lamp.
(2) The steel material should be of the same steel type as far as possible, and should be selected from the same lot.
If the steel type is different, the state of erosion may change in a subtle way. Even if the same erosion processing is done for SKD11 and the pre-hardened steel S55C, there may be subtle differences in the state of the undulations.
In addition, even if the same steel type is used, there is the danger of the finished state after texturing being different due to differences in the lot of the material or the direction of rolling of the material.
When a mold is prepared to yield multiple pieces of the product, or when there are many locations in which the mold is manufactured, or when the mold is produced simultaneously in Japan and other countries, it has been pointed out that there is the danger of the above cases occurring.
If the state of texturing becomes different, in order to carry out texturing again, it becomes necessary to carry out polishing again of the cavity surface which can lead to a huge loss of time.
(3) Particularly careful polishing is necessary for surfaces prepared by electric discharge machining.
Surfaces that are prepared by electric discharge machining will have a machining hardened layer that may have appeared, and hence it is recommended to carry out thorough polishing of such surfaces.

Solutions for Molding Defects (Silver Streaks)


Silver streaks are a phenomenon in which shining line shaped patterns appear on the surface of the molded product. These can be considered external appearance quality defects in exterior parts of consumer electrical products, automobiles, motorcycles, etc.
The cause of silver streaks is the air or gases contained in the molding material appearing on the surface of the molded product.
The following methods can be thought of as the countermeasures for solving the problem of silver streaks.

(1) Countermeasures related to molds1. Enhancing the function of air vents.
2. Making gate size larger.
3. Making the cold slag well larger

(2) Countermeasures related to the injection molding conditions1. Checking the preliminary drying conditions (temperature, drying time) of the molding material, and carrying out appropriate drying.
This is the most important countermeasure.
2. Making the injection speed lower and filling the cavity slowly.
3. Making the cylinder temperature lower.
4. Making the screw rotation speed lower.
5. Preventing stagnation of the plastic inside the cylinder.

(3) Countermeasures related to the molded product design1. Making the wall thickness of the molded product as uniform as possible.